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Thermo Scientific Chemicals
m-Anisidine, 98%
CAS: 536-90-3 | C7H9NO | 123.155 g/mol
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化學識別
CAS536-90-3
IUPAC Name3-methoxyaniline
Molecular FormulaC7H9NO
InChI KeyNCBZRJODKRCREW-UHFFFAOYSA-N
SMILESCOC1=CC=CC(N)=C1
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規格
規格表
規格表Assay (GC)≥97.5%
FormLiquid
Refractive Index1.5790-1.5830 @ 20?C
Appearance (Color)Pale yellow to dark red or dark brown
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
Solubility
Soluble in water(18g/L).
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.
Solubility
Soluble in water(18g/L).
Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only
General References:
- W. Preston Reeves,; Rufus M. King . A Convenient Method for Bromination of Aromatic Amines. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 1993, 23 (6), 855-859.
- Renuka K,; RowTNG,; Prasad BR,; Subramanian CK,;Bhattacharya, S .Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials - Evidence For The Control Of 2nd-Harmonic Generation Activities From The X-Ray Crystal-Structures Of The Complexes Of L-Tartaric Acid With M-Anisidine and P-Toluidine . Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials. 1995, 19 (1), 83-89..