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1,6-Heptadiyne, 97%, Thermo Scientific Chemicals
產品號碼: A11318.22
100 g, Each
化學識別
CAS
2396-63-6
IUPAC Name
hepta-1,6-diyne
Molecular Formula
C7H8
InChI Key
RSPZSDWVQWRAEF-UHFFFAOYSA-N
SMILES
C#CCCCC#C
規格
規格表Appearance (Color)
Clear colorless to yellow
Assay (GC)
≥96.0%
Form
Liquid
Refractive Index
1.4395-1.4445 @ 20?C
Identification (FTIR)
Conforms
說明
1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct.
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Haevy metal powder, heat. Refrigerate at (+4°C).
1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct.
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Haevy metal powder, heat. Refrigerate at (+4°C).
RUO – Research Use Only
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