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Dibenzyl carbonate, 98%, Thermo Scientific Chemicals
產品號碼: A11464.09
10 g, Each
化學識別
CAS
3459-92-5
IUPAC Name
dibenzyl carbonate
Molecular Formula
C15H14O3
InChI Key
PIZLBWGMERQCOC-UHFFFAOYSA-N
SMILES
O=C(OCC1=CC=CC=C1)OCC1=CC=CC=C1
規格
規格表Appearance (Color)
Clear colorless to white to pale yellow
Form
Liquid
Assay (GC)
≥97.5%
Identification (FTIR)
Conforms
Refractive Index
1.5460-1.5500 @ 20?C
說明
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.
Solubility
Sparingly Soluble (0.099 g/L) (25°C).
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.
Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. Dibenzyl carbonate (DBzlC) has been used to benzylate phenylacetonitrile, benzyl phenylacetate and phenol. Selective N, N-dibenzylation of primary aliphatic amines was carried with dibenzyl carbonate in the presence of phosphonium salts.
Solubility
Sparingly Soluble (0.099 g/L) (25°C).
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, heat.
RUO – Research Use Only
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