Triphenylsilane, 97%
Triphenylsilane, 97%
Triphenylsilane, 97%
Thermo Scientific Chemicals

Triphenylsilane, 97%

CAS: 789-25-3 | C18H15Si | 259.403 g/mol
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Quantity:
10 g
50 g
產品號碼 A11605.09
亦稱為 A11605-09
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Quantity:
10 g
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化學識別
CAS789-25-3
規格Specification Sheet規格表
Identification (FTIR)Conforms
Appearance (Color)White
Assay (GC)≥96.0%
FormCrystals or powder or crystalline powder or lumps
Melting Point (clear melt)42.0-48.0?C
Triphenylsilane acts as a reactant or reagent for catalytic hydrogen deuterium exchange reactions of silanes, to be oxidized by carbon nanotube-gold nanohybrids, for hydrolysis by ruthenium complexes, for hydrosilylation to produce enolsilanes, for synthesis of bromosilanes, for ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives. It is used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triphenylsilane acts as a reactant or reagent for catalytic hydrogen deuterium exchange reactions of silanes, to be oxidized by carbon nanotube-gold nanohybrids, for hydrolysis by ruthenium complexes, for hydrosilylation to produce enolsilanes, for synthesis of bromosilanes, for ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives. It is used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes.

Solubility
Soluble in methanol. Decomposes in water.

Notes
Air Sensitive. Incompatible with air and oxidizing agents.
RUO – Research Use Only

General References:

  1. George C Fortman; Heiko Jacobsen; Luigi Cavallo; Steven P Nolan. Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III) complexes. Chemical Communications.2011, 47 (34), 9723-9725.
  2. Jubi John; Edmond Gravel; Agnès Hagège; Haiyan Li; Thierry Gacoin; Eric Doris. Catalytic oxidation of silanes by carbon nanotube-gold nanohybrids. Angewandte Chemie. International edition in English.2011, 50 (33), 7533-7536.