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Benzyl 2,2,2-trichloroacetimidate, 98%, Thermo Scientific Chemicals
產品號碼: A12387.14
25 g, Each
化學識別
CAS
81927-55-1
IUPAC Name
benzyl 2,2,2-trichloroethanimidate
Molecular Formula
C9H8Cl3NO
InChI Key
HUZCTWYDQIQZPM-UHFFFAOYSA-N
SMILES
ClC(Cl)(Cl)C(=N)OCC1=CC=CC=C1
規格
規格表Appearance (Color)
Clear colorless to pale yellow
Refractive Index
1.5425-1.5465 @ 20?C
Assay (GC)
≥97.5%
Form
Liquid
說明
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Solubility
Miscible with cyclohexane/dichloromethane.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents and strong acids.
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Solubility
Miscible with cyclohexane/dichloromethane.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents and strong acids.
RUO – Research Use Only
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