Ethylene chlorophosphite, 97%

Name: Ethylene chlorophosphite, 97%
SKU: A12724.22

CAS: 822-39-9 | C2H4ClO2P | 126.476 g/mol

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產品號碼 A12724.22

亦稱為 A12724-22

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100 g

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化學識別

CAS822-39-9

IUPAC Name2-chloro-1,3,2-dioxaphospholane

Molecular FormulaC2H4ClO2P

InChI KeyOLSFRDLMFAOSIA-UHFFFAOYSA-N

SMILESClP1OCCO1

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規格

規格表

Refractive Index1.4890-1.4940 @ 20?C

Appearance (Color)Clear colorless to yellow

Assay (Titration ex Chloride)≥96.0 to ≤104.0%

FormLiquid

Ethylene chlorophosphite acts as a phosphitylating agent involved in the preparation of phosphocholine and spirophosphoranes. For example, it is used in the phosphorylation of p-tert-butyl(thia)calixarenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Ethylene chlorophosphite acts as a phosphitylating agent involved in the preparation of phosphocholine and spirophosphoranes. For example, it is used in the phosphorylation of p-tert-butyl(thia)calixarenes.

Notes
Store in cool place. Moisture sensitive. Incompatible with water.

RUO – Research Use Only

General References:

Peptide coupling reagent via the mixed anhydride; see Appendix 6: J. Am. Chem. Soc., 72, 5491 (1950).
In conjunction with triethyl phosphite, dehydrates primary carboxamides to nitriles, which has been applied in peptide chemistry: J. Am. Chem. Soc., 88, 2025 (1966).
Used in the coupling of arylamines with CS₂ to give diarylthioureas: Rev. Roum. Chim., 29, 329 (1984).
Stoikov, I. I.; Mostovaya, O. A.; Yantemirova, A. A.; Antipin, I. S.; Konovalov, A. I. Phosphorylation of p-tert-butyl (thia) calixarenes by ethylene chlorophosphite. Mendeleev Commun. 2012, 22 (1), 21-22.
Kibardina, L. K.; Dobrynin, A. B.; Burilov, A. R.; Pudovik, M. A. Reaction of N, N-Bis (2-hydroxy-1-naphthaldehyde)-ethylenediimine with ethylene chlorophosphite. Russ. J. Gen. Chem. 2011, 81 (8), 1728-1729.