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Thermo Scientific Chemicals
(S)-(-)-1-(1-Naphthyl)ethylamine, 99%
CAS: 10420-89-0 | C12H14N | 172.25 g/mol
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化學識別
CAS10420-89-0
IUPAC Name(1S)-1-(naphthalen-1-yl)ethan-1-aminium
Molecular FormulaC12H14N
InChI KeyRTCUCQWIICFPOD-VIFPVBQESA-O
SMILESC[C@H]([NH3+])C1=C2C=CC=CC2=CC=C1
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規格
規格表
規格表Appearance (Color)Clear colorless to yellow
Assay (GC)≥98.0% (non-U.S. specification)
Assay from Suppliers CofA≥98.0% (U.S. specification)
CommentMay darken on storage
CommentSpecification differs for U.S. and non-U.S. material where indicated
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(S)-(-)-1-(1-Naphthyl)ethylamine, (S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
(S)-(-)-1-(1-Naphthyl)ethylamine, (S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.
Solubility
Soluble in chloroform, ethanol.
Notes
Air Sensitive. Stable under recommended storage conditions. Keep away from acids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates.
(S)-(-)-1-(1-Naphthyl)ethylamine, (S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.
Solubility
Soluble in chloroform, ethanol.
Notes
Air Sensitive. Stable under recommended storage conditions. Keep away from acids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates.
RUO – Research Use Only
General References:
- JM Bonello.; FJ Williams. Aspects of enantioselective heterogeneous catalysis: Structure and reactivity of (S)-(-)-1-(1-naphthyl) ethylamine on Pt {111}. J. Am. Chem. Soc. 2003125 (9), 2723-2729.
- NW Alcock.; JM Brown.; DI Hulmes. Synthesis and resolution of 1-(2-diphenylphosphino-1-naphthyl) isoquinoline; a P N chelating ligand for asymmetric catalysis. Tetrahedron: Asymmetry. 19934 (4), 743-756.