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Thermo Scientific Chemicals
4-Bromophenylacetone, 98%
CAS: 6186-22-7 | C24H24N2O5S | 452.53 g/mol
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化學識別
CAS6186-22-7
IUPAC Namemethyl 2-{2-[N-(3,5-dimethylphenyl)benzenesulfonamido]acetamido}benzoate
Molecular FormulaC24H24N2O5S
InChI KeyCDUPPXGKUKTGLU-UHFFFAOYSA-N
SMILESCOC(=O)C1=CC=CC=C1NC(=O)CN(C1=CC(C)=CC(C)=C1)S(=O)(=O)C1=CC=CC=C1
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規格
規格表
規格表FormLiquid
Appearance (Color)Clear pale yellow to yellow
Refractive Index1.5560-1.5600 @ 20?C
Assay (GC)≥97.5%
4-Bromophenylacetone is used to prepare biphenyl-4-yl-acetone by reacting with phenylboronic acid using cesium fluoride as a reagent and palladium phosphine complex as a catalyst.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-Bromophenylacetone is used to prepare biphenyl-4-yl-acetone by reacting with phenylboronic acid using cesium fluoride as a reagent and palladium phosphine complex as a catalyst.
Solubility
Miscible with chloroform and dichloromethane. Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents, reducing agents and bases.
4-Bromophenylacetone is used to prepare biphenyl-4-yl-acetone by reacting with phenylboronic acid using cesium fluoride as a reagent and palladium phosphine complex as a catalyst.
Solubility
Miscible with chloroform and dichloromethane. Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents, reducing agents and bases.
RUO – Research Use Only
General References:
- Weidmann, V.; Ploog, J.; Kliewer, S.; Schaffrath, M.; Maison, W. Variants of the Prins Cyclization for the Synthesis of Terpenoid Spiroethers and Oxabicyclo[3.3.1]Nonane Derivatives. J. Org. Chem. 2014, 79 (21), 10123-10131.
- Sasnouski, G.; Lapanik, V.; Bezborodov, V.; Dabrowski, R.; Dziaduszek, J. Synthesis of fluoro substituted quaterphenyl liquid crystals. Phase Transitions 2014, 87 (8), 783-789.