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Thermo Scientific Chemicals
4-Chlorostyrene, 98+%, stab
CAS: 1073-67-2 | C8H7Cl | 138.59 g/mol
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化學識別
CAS1073-67-2
IUPAC Name1-chloro-4-ethenylbenzene
Molecular FormulaC8H7Cl
InChI KeyKTZVZZJJVJQZHV-UHFFFAOYSA-N
SMILESClC1=CC=C(C=C)C=C1
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規格
規格表
規格表Refractive Index1.5640-1.5670 @ 20°C
Solution Test10% in Diethyl ether: Clear
Solution Test10% in Methanol: Clear
Identification (FTIR)Conforms
Appearance (Color)Clear colorless to yellow to orange
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4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.
Solubility
Immiscible with water.
Notes
Incompatible with acids, bases, oxidizing agents, halogens, metal salts and polymerizing initiators. Store in a cool place.
4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine.
Solubility
Immiscible with water.
Notes
Incompatible with acids, bases, oxidizing agents, halogens, metal salts and polymerizing initiators. Store in a cool place.
RUO – Research Use Only
General References:
- Dhakshinamoorthy, A.; Latorre-Sanchez, M.; Asiri, A. M.; Primo, A.; Garcia, H. Sulphur-doped graphene as metal-free carbocatalysts for the solventless aerobic oxidation of styrenes. Catal. Commun. 2015, 65, 10-13.
- Wang, B.; Lee, Y. M.; Seo, M. S.; Nam, W. Mononuclear Nonheme Iron(III)-Iodosylarene and High-Valent Iron-Oxo Complexes in Olefin Epoxidation Reactions. Angew. Chem. Int. Ed. 2015, 54 (40), 11740-11744.