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Thermo Scientific Chemicals
4-Allyl-1,6-heptadien-4-ol, 99%
CAS: 10202-75-2 | C10H16O | 152.237 g/mol
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化學識別
CAS10202-75-2
IUPAC Name4-(prop-2-en-1-yl)hepta-1,6-dien-4-ol
Molecular FormulaC10H16O
InChI KeySUXQWOWVXDXQSE-UHFFFAOYSA-N
SMILESOC(CC=C)(CC=C)CC=C
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規格
規格表
規格表Appearance (Color)Clear colorless
FormLiquid
Assay (GC)≥98.5%
Refractive Index1.4695-1.4725 @ 20?C
A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.
Solubility
Soluble in water.
Notes
Store at room temperature. Incompatible with strong oxidizing agents.
A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.
Solubility
Soluble in water.
Notes
Store at room temperature. Incompatible with strong oxidizing agents.
RUO – Research Use Only
General References:
- Hongjun Ren.; Guillaume Dunet.; Peter Mayer.; Paul Knochel. Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents.J. Am. Chem. Soc. 2007, 129 (17),5376-5377 .
- Robert J. Hinkle.; Alessandra C. Leri.; Geoffrey A. David. ;Whitney M. Erwin. Addition of Benzylzinc Halides to Alkenyl(phenyl)iodonium Triflates: Stereoselective Synthesis of Trisubstituted Alkenes.Org. Lett.. 2000, 2 (11),1521-1523 .