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Thermo Scientific Chemicals
1,2-Bis(diphenylphosphino)benzene, 98%
CAS: 13991-08-7 | C30H24P2 | 446.47 g/mol
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化學識別
CAS13991-08-7
IUPAC Name[2-(diphenylphosphanyl)phenyl]diphenylphosphane
Molecular FormulaC30H24P2
InChI KeyNFRYVRNCDXULEX-UHFFFAOYSA-N
SMILESC1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
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規格
規格表
規格表FormCrystals or powder or crystalline powder
Assay (unspecified)≥97.5%
Identification (FTIR)Conforms
Melting Point184-190°C
Appearance (Color)White
It acts as a ligand for Baeyer-Villiger Oxidation, cycloadditions and reductions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It acts as a ligand for Baeyer-Villiger Oxidation, cycloadditions and reductions.
Solubility
Insoluble in water.
Notes
Air sensitive. Store away from air and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
It acts as a ligand for Baeyer-Villiger Oxidation, cycloadditions and reductions.
Solubility
Insoluble in water.
Notes
Air sensitive. Store away from air and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
RUO – Research Use Only
General References:
- Akira Tsuboyama, et al. Photophysical Properties of Highly Luminescent Copper(I) Halide Complexes Chelated with 1,2-Bis(diphenylphosphino)benzene.Inorg. Chem.,200746(6), 1992-2001.
- Takuji Hatakeyama, et al. Iron-catalyzed fluoroaromatic coupling reactions under catalytic modulation with 1,2-bis(diphenylphosphino)benzene.Chem. Commun.,2009,(10), 1216-1218.