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Thermo Scientific Chemicals
Allylchlorodimethylsilane, 94%
CAS: 4028-23-3 | C5H11ClSi | 134.678 g/mol
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化學識別
CAS4028-23-3
IUPAC Namechlorodimethyl(prop-2-en-1-yl)silane
Molecular FormulaC5H11ClSi
InChI KeyKMVZWUQHMJAWSY-UHFFFAOYSA-N
SMILESC[Si](C)(Cl)CC=C
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規格
規格表
規格表Appearance (Color)Clear colorless
FormLiquid
Assay (GC)≥92.0%
Identification (FTIR)Conforms
Refractive Index1.4260-1.4320 @ 20?C
Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1?,4,4?-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1′,4,4′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.
Solubility
Soluble in most organic solvents; reacts with alcohols, amines, and water.
Notes
Moisture sensitive. Store away from strong oxidizing agents, strong bases, water/ moisture.
Allylchlorodimethylsilane is used in the synthesis of cyclo-1,1′,4,4′-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene, silylating agent for steroids for analysis by GC-MS. Also used in the preparation of phenylenebis(silanediyl triflates), useful synthons for organosilicon polymers, O-silylation of phenyl sulfones.
Solubility
Soluble in most organic solvents; reacts with alcohols, amines, and water.
Notes
Moisture sensitive. Store away from strong oxidizing agents, strong bases, water/ moisture.
RUO – Research Use Only
General References:
- K. A. Abboud; D. W. Smith Jnr and K. B. Wagener. 3Structure of cyclo-1,1',4,4'-bis(1,1,3,3-tetramethyl-1,3-disiloxanediyl)dibenzene. Acta Cryst.. 1993, 53 (49), 1845-1848.
- Yoshimoto Abe; Takahiro Gunji. Oligo- and polysiloxanes. Progress in Polymer Science. 2004, 29 (3), 149-182.
- Reagent for the derivatization of steroids for GC-MS: J. Chromat., 129, 384 (1976); J. Chromat. Sci., 17, 115 (1979). See Appendix 4.