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Triethyl 2-phosphonopropionate, 98%, Thermo Scientific Chemicals
產品號碼: B23261.09
10 g, Each
化學識別
CAS
3699-66-9
IUPAC Name
ethyl 2-(diethoxyphosphoryl)propanoate
Molecular Formula
C9H19O5P
InChI Key
BVSRWCMAJISCTD-UHFFFAOYNA-N
SMILES
CCOC(=O)C(C)P(=O)(OCC)OCC
規格
規格表Identification (FTIR)
Conforms
Refractive Index
1.4295-1.4335 @ 20?C
Appearance (Color)
Clear colorless
Form
Liquid
Assay (GC)
≥97.5%
說明
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
Solubility
Miscible with chloroform and methanol.
Notes
Incompatible with strong bases.
Triethyl 2-phosphonopropionate is used as a reactant in intramolecular conjugate addition for the synthesis of floresolide B, enantioselective synthesis of spiroindane di-methyl acetic acid and in stereo selective intramolecular Diels-Alder reactions. It plays an important role in Horner-Wadsworth-Emmons reactions and chemoenzymatic one-pot synthesis of gamma-butyrolactones. It is also used in the preparation of 3-[2]furyl-2-methyl-acrylic acid ethyl ester by reacting with furfural.
Solubility
Miscible with chloroform and methanol.
Notes
Incompatible with strong bases.
RUO – Research Use Only
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