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Thermo Scientific Chemicals
Furan-2-boronic acid, 97%
CAS: 13331-23-2 | C4H5BO3 | 111.891 g/mol
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化學識別
CAS13331-23-2
IUPAC Name(furan-2-yl)boronic acid
Molecular FormulaC4H5BO3
InChI KeyPZJSZBJLOWMDRG-UHFFFAOYSA-N
SMILESOB(O)C1=CC=CO1
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規格
規格表
規格表FormCrystals or powder or crystalline powder
Assay (Aqueous acid-base Titration)≥96.0%
Assay (HPLC)≥96.0%
Proton NMRConforms to structure
Appearance (Color)Pale cream to cream
It is used in Suzuki reaction for generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is used in Suzuki reaction for generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes.
Solubility
Slightly soluble in water.
Notes
Air sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
It is used in Suzuki reaction for generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes.
Solubility
Slightly soluble in water.
Notes
Air sensitive. Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
RUO – Research Use Only
General References:
- Michael J. Burns, et al. Simple Palladium(II) Precatalyst for Suzuki-Miyaura Couplings: Efficient Reactions of Benzylic, Aryl, Heteroaryl, and Vinyl Coupling Partners.Org. Lett.,2007,9(26), 5397-5400.
- Khokan Samanta, et al. A generalized route for the synthesis of β-furyl-α,β-unsaturated aldehydes through Suzuki reactions.Tetrahedron Lett.,2008,49(9), 1461-1464.
- Undergoes an asymmetric boronic acid Mannich reaction with aldehydes in the presence of the chiral template (S)-5-phenylmorpholine-2-one to give substituted furfurylamines with high diastereomeric excess: Chem. Commun., 1953 (1996); J. Chem. Soc., Perkin 1, 2982 (2000):