Methyl 1-cyclohexene-1-carboxylate, 97%

Name: Methyl 1-cyclohexene-1-carboxylate, 97%
SKU: B25568.14

CAS: 18448-47-0 | C8H12O2 | 140.182 g/mol

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25 g

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產品號碼 B25568.14

亦稱為 B25568-14

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25 g

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化學識別

CAS18448-47-0

IUPAC Namemethyl cyclohex-1-ene-1-carboxylate

Molecular FormulaC8H12O2

InChI KeyKXPWRCPEMHIZGU-UHFFFAOYSA-N

SMILESCOC(=O)C1=CCCCC1

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規格

規格表

Appearance (Color)Clear colorless to pale yellow

Refractive Index1.4745-1.4795 @20?C

FormLiquid

Assay (GC)≥96.0%

Identification (FTIR)Conforms

Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.

Solubility
Immiscible with water.

Notes
Incompatible with strong oxidizing agents and bases.

RUO – Research Use Only

General References:

Johnson, M. R.; Gauuan, J. F.; Guo, C.; Guzzo, P. R.; Le, V. D.; Shenoy, R. A.; Hamby, J.; Roark, H.; Stier, M.; Mangette, J. E. Synthesis and Characterization of Novel Bi-and Tricyclic α-Amino Acids. Synth. Commun. 2011, 41 (18), 2769-2793.
Tian, G. Q.; Yang, J.; Rosa-Perez, K. γ-Oxygenation of α, β-Unsaturated Esters by Vinylogous O-Nitroso Mukaiyama Aldol Reaction. Org. Lett. 2010, 12 (21), 5072-5074.