(Pentafluoroethyl)trimethylsilane, 97%

Name: (Pentafluoroethyl)trimethylsilane, 97%
SKU: H25775.06

CAS: 124898-13-1 | C5H9F5Si | 192.204 g/mol

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產品號碼 H25775.06

亦稱為 H25775-06

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5 g

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化學識別

CAS124898-13-1

IUPAC Nametrimethyl(1,1,2,2,2-pentafluoroethyl)silane

Molecular FormulaC5H9F5Si

InChI KeyMTPVUVINMAGMJL-UHFFFAOYSA-N

SMILESC[Si](C)(C)C(F)(F)C(F)(F)F

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規格

規格表

Appearance (Color)Clear colorless

FormLiquid

Assay (GC)≥96.0%

Refractive Index1.3230-1.3280 @ 20?C

(Pentafluoroethyl)trimethylsilane acts as a silicon-based fluorinating reagent for trifluoromethylation of carbonyls and ethylene diamines. It is also employed as a precursor for metal-mediated trifluoromethylation of aromatic, heteroaromatic and vinyl substrates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(Pentafluoroethyl)trimethylsilane acts as a silicon-based fluorinating reagent for trifluoromethylation of carbonyls and ethylene diamines. It is also employed as a precursor for metal-mediated trifluoromethylation of aromatic, heteroaromatic and vinyl substrates.

Solubility
Miscible with tetrahydrofuran.

Notes
Moisture sensitive. Incompatible with oxidizing agents.

RUO – Research Use Only

General References:

Jin, G.; Zhang, X.; Fu, D.; Dai, W.; Cao, S. Mild and metal-free trifluoromethylation and pentafluoroethylation of gem-difluoroalkenes with TMSCF₃ and TMSCF₂CF₃. Tetrahedron 2015, 71 (41), 7892-7899.
O’Duill, M.; Dubost, E.; Pfeifer, L.; Gouverneur, V. Cross-Coupling of [2-Aryl-1,1,2,2-tetrafluoroethyl](trimethyl)silanes with Aryl Halides. Org. Lett. 2015, 17 (14), 3466-3469.