1,1,4,7,10,10-Hexamethyltriethylenetetramine, 97%
1,1,4,7,10,10-Hexamethyltriethylenetetramine, 97%
1,1,4,7,10,10-Hexamethyltriethylenetetramine, 97%
Thermo Scientific Chemicals

1,1,4,7,10,10-Hexamethyltriethylenetetramine, 97%

CAS: 3083-10-1 | C12H30N4 | 230.40 g/mol
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Quantity:
1 g
5 g
25 g
產品號碼 H56089.03
亦稱為 H56089-03
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Quantity:
1 g
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化學識別
CAS3083-10-1
IUPAC Name2,5,8,11-tetramethyl-2,5,8,11-tetraazadodecane
Molecular FormulaC12H30N4
InChI KeyDWFKOMDBEKIATP-UHFFFAOYSA-N
SMILESCN(C)CCN(C)CCN(C)CCN(C)C
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規格Specification Sheet規格表
Assay (GC)96.0% min

1,1,4,7,10,10-Hexamethyltriethylenetetramine may be used as reagent in the synthesis of ideal linear random copolymers containing both vinyl polymer and polyester units in a single polymer chain.1 1,1,4,7,10,10-Hexamethyltriethylenetetramine complexed with CuBr constitutes catalytic complex, used in the copolymerization of poly[ε-caprolactone] with N,N-dimethylamino-2-ethyl methacrylate monomers by atom-transfer radical polymerization (ATRP).2 It may be used as catalyst in the aqueous surface-initiated-ATRP to grow poly(N,N-dimethylacrylamide) (PDMA).3

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1,4,7,10,10-Hexamethyltriethylenetetramine may be used as reagent in the synthesis of ideal linear random copolymers containing both vinyl polymer and polyester units in a single polymer chain.1 1,1,4,7,10,10-Hexamethyltriethylenetetramine complexed with CuBr constitutes catalytic complex, used in the copolymerization of poly[ε-caprolactone] with N,N-dimethylamino-2-ethyl methacrylate monomers by atom-transfer radical polymerization (ATRP).2 It may be used as catalyst in the aqueous surface-initiated-ATRP to grow poly(N,N-dimethylacrylamide) (PDMA).3

Solubility
Soluble in water.

Notes
Incompatible with oxidizing agents. Store at room temperature.
RUO – Research Use Only

General References:

  1. Jianhui Xia.; Krzysztof Matyjaszewski. Controlled/Living Radical Polymerization. Atom Transfer Radical Polymerization Using Multidentate Amine Ligands.Macromolecules. 1997, 30 (25),7697-7700.
  2. Mariko Goto.; Koh-ichi Akimoto.; Kazumasa Aoki.; Mitsuru Shindo.; Kenji Koga. 1,1,4,7,10-10-Hexamethyltriethylenetetramine: a reagent to enhance the rate of alkylation reaction of the lithium enolate of 1-tetralone with alkyl halides. Tetrahedron Lett. 1999, 40 (46),8129-8132.