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Thermo Scientific Chemicals
tert-Butyl cyanoacetate, 98%
CAS: 1116-98-9 | C7H11NO2 | 141.17 g/mol
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化學識別
CAS1116-98-9
規格
規格表
規格表FormLiquid or viscous liquid
Assay (GC)≥97.5%
Appearance (Color)Clear colorless to white to yellow
Refractive Index1.4180-1.4220 @ 20?C
tert-Butyl cyanoacetate is used in the synthesis of vinylogous urea. It is also used as a new additive for the sugar nucleoside base coupling step en route to DAPD with improved β-selectivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
tert-Butyl cyanoacetate is used in the synthesis of vinylogous urea. It is also used as a new additive for the sugar nucleoside base coupling step en route to DAPD with improved β-selectivity.
Solubility
Difficult to mix.
Notes
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.
tert-Butyl cyanoacetate is used in the synthesis of vinylogous urea. It is also used as a new additive for the sugar nucleoside base coupling step en route to DAPD with improved β-selectivity.
Solubility
Difficult to mix.
Notes
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.
RUO – Research Use Only
General References:
- Ivan L Pinto.; Richard L Jarvest.; Halina T Serafinowska. The synthesis of 5-alkoxy and 5-amino substituted thiophenes. Tetrahedron Letters. 2000, 41, (10), 1597-1600.
- Reenu Sirohia.; Dong Hee Kimb.; Soo-Chang Yub.; Sang Hee Lee. Novel di-anchoring dye for DSSC by bridging of two mono anchoring dye molecules: A conformational approach to reduce aggregation. Dyes and Pigments. 2012, 92, (3), 1132-1137.
- Alternative to Ethyl cyanoacetate, A11498, permitting non-hydrolytic decarboxylative cleavage of the ester group: Arkiv. Kemi., 23, 453 (1965); cf J. Am. Chem. Soc., 74, 831 (1952).