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Thermo Scientific Chemicals
Butadiene monoxide, 98%
CAS: 930-22-3 | C4H6O | 70.091 g/mol
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化學識別
CAS930-22-3
IUPAC Name2-ethenyloxirane
Molecular FormulaC4H6O
InChI KeyGXBYFVGCMPJVJX-UHFFFAOYNA-N
SMILESC=CC1CO1
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規格
規格表
規格表Appearance (Color)Clear colorless
Assay (GC)≥97.5%
Refractive Index1.4155-1.4200 @ 20?C
Identification (FTIR)Conforms
FormLiquid
Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.
Solubility
Miscible with ethanol, ethyl ether, benzene and organic solvents.
Notes
Moisture sensitive. Store in cool place. Incompatible with acids, bases and oxidizing agents.
Butadiene monoxide is used as key starting material for the synthesis of (-)-bulgecinine and (+)-broussonetine G.
Solubility
Miscible with ethanol, ethyl ether, benzene and organic solvents.
Notes
Moisture sensitive. Store in cool place. Incompatible with acids, bases and oxidizing agents.
RUO – Research Use Only
General References:
- Reaction with allyl bromide, mediated by In metal, affords diallylmethanol: Tetrahedron Lett., 44, 2911 (2003):
- Li, G.; Feng, X.; Du, H. Palladium-catalyzed asymmetric allylic amination of racemic butadiene monoxide with isatin derivatives. Org. Biomol. Chem. 2015, 13 (20), 5826-5830.
- Mao, W.; He, H. H.; Gu, J. Q.; Chen, W.; Wu, K.; Tok, E. S.; Xu, G. Q. Preservation of epoxy groups on surfaces in the covalent attachment of butadiene monoxide on Si(111)-(7x7): the effect of a vinyl substituent. Chem. Commun. 2015, 51 (75), 14195-14198.