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Thermo Scientific Chemicals
Phenyl formate, 95%
CAS: 1864-94-4 | C7H6O2 | 122.123 g/mol
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化學識別
CAS1864-94-4
IUPAC Namephenyl formate
Molecular FormulaC7H6O2
InChI KeyGEOWCLRLLWTHDN-UHFFFAOYSA-N
SMILESO=COC1=CC=CC=C1
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規格
規格表
規格表Refractive Index1.5060-1.5150 @ 20?C
FormLiquid
CommentRI quite variable with impurity profile
Appearance (Color)Clear colorless
Assay (GC)≥94.0%
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Phenyl formate is widely used in the palladium-catalyzed carbonylation of aryl, alkenyl and allyl halides. It is also used as a reagent for the formylation of amines.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Phenyl formate is widely used in the palladium-catalyzed carbonylation of aryl, alkenyl and allyl halides. It is also used as a reagent for the formylation of amines.
Solubility
Immiscible with water, alcohol, ether and benzene.
Phenyl formate is widely used in the palladium-catalyzed carbonylation of aryl, alkenyl and allyl halides. It is also used as a reagent for the formylation of amines.
Solubility
Immiscible with water, alcohol, ether and benzene.
RUO – Research Use Only
General References:
- Reagent for the formylation of amines in high yield: J. Org. Chem., 36, 3238 (1971).
- Ren, W.; Chang, W.; Wang, Y.; Li, J.; Shi, Y. Pd-Catalyzed Regiodivergent Hydroesterification of Aryl Olefins with Phenyl Formate. Org. Lett. 2015, 17 (14), 3544-3547.
- Konishi, H.; Nagase, H.; Manabe, K. Concise synthesis of cyclic carbonyl compounds from haloarenes using phenyl formate as the carbonyl source. Chem. Commun. 2015, 51 (10), 1854-1857.