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Thermo Scientific Chemicals
Cyclopropyl phenyl ketone, 97%
CAS: 3481-02-5 | C10H10O | 146.19 g/mol
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化學識別
CAS3481-02-5
IUPAC Namecyclopropyl(phenyl)methanone
Molecular FormulaC10H10O
InChI KeyPJRHFTYXYCVOSJ-UHFFFAOYSA-N
SMILESO=C(C1CC1)C1=CC=CC=C1
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規格
規格表
規格表FormLiquid
Assay (GC)≥96.0%
Appearance (Color)Clear colorless to yellow
Identification (FTIR)Conforms
Refractive Index1.5510-1.5565 @ 20?C
Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
Solubility
Insoluble in water.
Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
Cyclopropyl phenyl ketone is used to prepare α-cyclopropylstyrene by the Wittig reaction in dimethyl sulfoxide. It is also used as starting reagent during the (Z)-titanium enolate formation from cyclopropyl ketones via TiCl4-n-Bu4NI-induced ring opening reaction.
Solubility
Insoluble in water.
Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.
RUO – Research Use Only
General References:
- W. J. Close. An Improved Synthesis of Cyclopropyl Phenyl Ketone and Related Substances. J. Am. Chem. Soc. 1957, 79 (6), 1455-1458.
- Frank J. Piehl.; Weldon G. Brown. Alkylation of Cyclopropyl Phenyl Ketone. J. Am. Chem. Soc. 1953, 75(20), 5023-5026.