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Thermo Scientific Chemicals
Vinyltrimethylsilane, 97%
CAS: 754-05-2 | C5H12Si | 100.236 g/mol
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化學識別
CAS754-05-2
IUPAC Nameethenyltrimethylsilane
Molecular FormulaC5H12Si
InChI KeyGCSJLQSCSDMKTP-UHFFFAOYSA-N
SMILESC[Si](C)(C)C=C
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規格
規格表
規格表Appearance (Color)Clear colorless
FormLiquid
Assay (GC)>96.0%
Refractive Index1.3885-1.3935 @ 20?C
Solution TestClear (10% in diethyl ether)
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Vinyltrimethylsilane is used in semiconductor processing. It is involved in the Preparation of silyl-ethers by Rh(I) catalysis. Further, it is used in the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Vinyltrimethylsilane is used in semiconductor processing. It is involved in the Preparation of silyl-ethers by Rh(I) catalysis. Further, it is used in the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.
Solubility
Miscible with tetrahydrofuran, diethyl ether, benzene and dichloromethane.
Notes
Store in a cool place. Hygroscopic. Incompatible with strong oxidizing agents, strong acids and strong alkalis (bases).
Vinyltrimethylsilane is used in semiconductor processing. It is involved in the Preparation of silyl-ethers by Rh(I) catalysis. Further, it is used in the preparation of trimethylsilylethyl sulfoxides which in the presence of fluoride ion generate sulfenate nucleophiles.
Solubility
Miscible with tetrahydrofuran, diethyl ether, benzene and dichloromethane.
Notes
Store in a cool place. Hygroscopic. Incompatible with strong oxidizing agents, strong acids and strong alkalis (bases).
RUO – Research Use Only
General References:
- Szudkowska-Fratczak, J.; Marciniec, B.; Hreczycho, G.; Kubicki, M.; Pawluc, P. Ruthenium-Catalyzed Silylation of 1,3-Butadienes with Vinylsilanes. Org. Lett. 2015, 17 (10), 2366-2369.
- Szudkowska-Fratczak, J.; Zaranek, M.; Hreczycho, G.; Kubicki, M.; Grabarkiewicz, T.; Pawluc, P. A silicon-assisted synthesis of (E)-beta-haloenamides from N-vinylamides. Appl. Organomet. Chem. 2015, 29 (5), 270-275.