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Thermo Scientific Chemicals
(Chloromethyl)cyclopropane, 97%
CAS: 5911-08-0 | C4H7Cl | 90.55 g/mol
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化學識別
CAS5911-08-0
規格
規格表
規格表Appearance (Color)Clear colorless to white to pale yellow
FormLiquid
Assay (GC)≥96.0%
Refractive Index1.4330-1.4390 @ 20?C
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Solubility
Not miscible in water.
Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4′-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
Solubility
Not miscible in water.
Notes
Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.
RUO – Research Use Only
General References:
- V.F.Kalasinsky; C. J.Wurrey. Vibrational spectra and conformations of (chloromethyl)cyclopropane and epichlorohydrin. Journal of Raman Spectroscopy. 1980, 9,(5), 315-323.
- N.Heineking; J.U.Grabow; I.Merke. Molecular beam Fourier transform microwave spectra of (chloromethyl)cyclopropane and (chloromethyl)oxirane. Journal of Molecular Structure. 2002, 612,(2-3), 231-244.