2-Butanone oxime, 99%
2-Butanone oxime, 99%
2-Butanone oxime, 99%
Thermo Scientific Chemicals

2-Butanone oxime, 99%

CAS: 96-29-7 | C4H9NO | 87.12 g/mol
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產品號碼 L08196.AP
亦稱為 L08196-AP
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500 mL
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化學識別
CAS96-29-7
IUPAC Name(E)-N-(butan-2-ylidene)hydroxylamine
Molecular FormulaC4H9NO
InChI KeyWHIVNJATOVLWBW-SNAWJCMRSA-N
SMILESCC\C(C)=N\O
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規格Specification Sheet規格表
FormLiquid or viscous liquid
Refractive Index1.4425-1.4455 @ 20?C
Assay (GC)≥98.5%
Appearance (Color)Clear colorless
2-Butanone oxime was employed as reagent and solvent in the syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes. It was also used in the synthesis of novel acetaldiimine cobalt complex, [CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}]. Methyl ethyl ketoxime is used primarily as an antiskinning agent in alkyd coating resins

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-Butanone oxime was employed as reagent and solvent in the syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes. It was also used in the synthesis of novel acetaldiimine cobalt complex, [CoI2{((CH3CH2)(CH3)C=NO)2C(CH3)2}]. Methyl ethyl ketoxime is used primarily as an antiskinning agent in alkyd coating resins

Solubility
Soluble in water at 20°C 114 g/L. Soluble in most organic solvents .

Notes
Store away from acids and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Keep ignition sources away.
RUO – Research Use Only

General References:

  1. Maximilian N Kopylovich, et al. Single-pot template transformations of cyanopyridines on a Pd(II) centre: syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes and their catalytic activity for microwave-assisted Suzuki-Miyaura and Heck reactions. Dalton Trans.,2009,163074-3084.
  2. Hierso J-C, et al. Cobalt-Assisted Condensation of 2-Butanone Oxime and Acetone: Synthesis and X-ray Structure of the Novel Acetaldiimine Complex [CoI2 {((CH3CH2)(CH3) C= NO) 2C (CH3) 2}].Eur. J. Inorg. Chem.,2000,2000(12), 2459-62.