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Thermo Scientific Chemicals
Methyl 3-bromopropionate, 97%
CAS: 3395-91-3 | C4H7BrO2 | 167.00 g/mol
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化學識別
CAS3395-91-3
IUPAC Namemethyl 3-bromopropanoate
Molecular FormulaC4H7BrO2
InChI KeyKQEVIFKPZOGBMZ-UHFFFAOYSA-N
SMILESCOC(=O)CCBr
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規格
規格表
規格表Appearance (Color)Clear, coloorless to very pale yellow
FormLiquid
Assay (GC)>96.0%
Refractive Index1.4555-1.4605 @ 20?c
Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones. It can react with 2-Methyl-1H-benzoimidazole to get 1-(2-Methoxycarbonylethyl)-2-methylbenzimidazole.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones. It can react with 2-Methyl-1H-benzoimidazole to get 1-(2-Methoxycarbonylethyl)-2-methylbenzimidazole.
Solubility
Immiscible in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.
Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones. It can react with 2-Methyl-1H-benzoimidazole to get 1-(2-Methoxycarbonylethyl)-2-methylbenzimidazole.
Solubility
Immiscible in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.
RUO – Research Use Only
General References:
- Adriana Pohlmann; Vincent Schanen; Dominique Guillaume; Jean-Charles Quirion; and Henri-Philippe Husson. Efficient Synthesis of Conformationally Constrained Peptidomimetics Containing 2-Oxopiperazines1. J. Org. Chem, 1997, 62, (4), 1016-1022.
- RenĆsuk; Zhong Hua; Mohamed Abdou; Christoph Kratky. Samarium diiodide promoted spirolactonization of cycloalkanones. Tetrahedron. 1991, 47, (34), 7037-7044.