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Thermo Scientific Chemicals
Cerium(IV) trifluoromethanesulfonate, 98%
CAS: 107792-63-2 | C4CeF12O12S4 | 736.37 g/mol
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CAS107792-63-2
Chemical Name or MaterialCerium(IV) trifluoromethanesulfonate
DOT InformationHazard Class: 8; Packaging Group: III
EINECS Number000-000-0
Formula Weight736.39
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Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers
Solubility
Soluble in water.
Notes
Hygroscopic. Store in a cool, dry place in a tightly closed containers. Stable under recommended storage conditions. Incompatible with oxidizing agents and moisture.
Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers
Solubility
Soluble in water.
Notes
Hygroscopic. Store in a cool, dry place in a tightly closed containers. Stable under recommended storage conditions. Incompatible with oxidizing agents and moisture.
RUO – Research Use Only
General References:
- Tsuneo Imamoto; Yasuhiro Koide; Susumu Hiyama. Cerium(IV) Trifluoromethanesulfonate as a Strong Oxidizing Agent. Chemistry Letters. 1990, 19(8),1445-1446
- Giuseppe Bartoli; Giovanna Cupone; Renato Dalpozzo; Antonio De Nino; Loredana Maiuolo; Antonio Procopio; Letizia Sambri; Antonio Tagarelli. Deprotection of t-butyldimethylsilyl ethers promoted by cerium(IV) triflate. Tetrahedron Letters. 2002, 43(34), 5945-5947.
- Catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers: Tetrahedron Lett., 43, 5945 (2002).
- The uses of rare-earth metal triflates in organic synthesis have been reviewed by S. Kobayashi: Synlett, 689 (1994); Chem. Rev., 102, 2227 (2002).