cis-2-Butene-1, 4-diol is used as a probe for studying isomerization versus hydrogenation and hydrogenolysis reactions. (DPCB-OMe) efficiently catalyzes cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds to give 2-vinyl-2,3-dihydrofurans in good to high yields. Grubbs's cross metathesis of eugenol with cis-2-butene-1, 4-diol to make a natural product, an organometallic experiment.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Anwendungen
Cis-2-buten-1,4-diol wird als Sonde für die Untersuchung der Isomerisierung im Vergleich zur Hydrierung und Hydrysereaktionen verwendet. (DPCB-OMe) katalysiert effizient die Cyclodehydrierung von cis-2-buten-1,4-diol mit aktiven Methylenverbindungen, um 2-Vinyl-2,3-dihydrofuran in guten bis hohen Ausbeuten zu ergeben. Grubbs′s cross metathesis of eugenol with cis-2-butene-1, 4-diol to make a natural product, an organometallic experiment.
Löslichkeit
Wasserlöslich.
Hinweise
Kühl lagern. Behälter an einem trockenen und gut belüfteten Ort dicht verschlossen halten. Von starken Oxidationsmitteln fernhalten.
RUO – Research Use Only
Allgemeine Referenzen:
- Chun-xiu Pan,; Xiu-zhu Xu,; Hong-mei He,; Xiao-jun Cai,; Xue-jun Zhang. Separation and identification of cis and trans isomers of 2-butene-1,4-diol and lafutidine by HPLC and LC-MS.. Journal of Zhejiang University (Science B). 2005, 6 (1), 74-78 .
- Hiromi Murakami,; Yukio Matsui,; Fumiyuki Ozawa,; Masaaki Yoshifuji. Cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds catalyzed by a diphosphinidenecyclobutene-coordinated palladium complex . Journal of Organometallic Chemistry. 2006, 691 (14) ,3151-3156.