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Thermo Scientific Chemicals

(+/-)-Benzyloxycarbonyl-Alpha-Phosphonoglycin-Trimethyl-Ester, 97 %, Thermo Scientific Chemicals

Katalognummer: B22506.06
5 g, Each
(+/-)-Benzyloxycarbonyl-Alpha-Phosphonoglycin-Trimethyl-Ester, 97 %, Thermo Scientific Chemicals
(+/-)-Benzyloxycarbonyl-Alpha-Phosphonoglycin-Trimethyl-Ester, 97 %, Thermo Scientific Chemicals
(+/-)-Benzyloxycarbonyl-Alpha-Phosphonoglycin-Trimethyl-Ester, 97 %, Thermo Scientific Chemicals
Zertifikate
Thermo Scientific Chemicals

(+/-)-Benzyloxycarbonyl-Alpha-Phosphonoglycin-Trimethyl-Ester, 97 %, Thermo Scientific Chemicals

Katalognummer: B22506.06
5 g, Each
Menge
Zertifikate
Katalognummer: B22506.06
auch als B22506-06 bezeichnet
Preis (EUR)
144,90 Online-Preis
161,00
Each
Menge
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Chemikalien-Kennzeichnungen

CAS
88568-95-0
IUPAC Name
methyl (2S)-2-{[(benzyloxy)carbonyl]amino}-2-(dimethoxyphosphoryl)acetate
Molecular Formula
C13H18NO7P
InChI Key
GSYSFVSGPABNNL-NSHDSACASA-N
SMILES
COC(=O)[C@@H](NC(=O)OCC1=CC=CC=C1)P(=O)(OC)OC

Spezifikationen

DatenblattDatenblatt
Assay (unspecified)
(by Carbon EA) : >96.0 to<104.0%
Elemental Analysis
(Carbon) : 45.25-49.01% (Theory 47.14%)
Elemental Analysis
(Hydrogen) : 5.25-5.69% (Theory 5.48%)
Proton NMR
Conforms to structure
Phosphorus-31 NMR
Conforms to structure

Beschreibung

(±)-Z-α-Phosphonoglycine trimethyl ester is the starting material for the synthesis of (Z)-dehydroamino acids by Wittig-Horner reaction with aldehydes, the dehydroamino acids can be stereo selectively reduced to amino acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
(±)-Z-α-Phosphonoglycin-Trimethylester ist das Ausgangsmaterial für die Synthese von (Z)-Dehydrominsäuren durch die Wittig-Horner-Reaktion mit Aldehyden, die Dehydrominsäuren können stereoselektiv auf Aminosäuren reduziert werden.

Löslichkeit
Löslich in Methanol.

Hinweise
Kühl und trocken in dicht verschlossenen Behältern lagern. Von starken Oxidationsmitteln fernhalten.
RUO – Nur für Forschungszwecke

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    Sicherheit und Handhabung


    Classification of the substance or mixture
    CLP classification - Regulation(EC) No 1272/2008
    Skin Corrosion/Irritation
    Category 2
    Serious Eye Damage/Eye Irritation
    Category 2
    Specific target organ toxicity - (single exposure)
    Category 3
    Label Elements
    Signal Word

    Warning

    Hazard Statements

    H315 - Causes skin irritation

    H319 - Causes serious eye irritation

    H335 - May cause respiratory irritation

    Precautionary Statements

    P261 - Avoid breathing dust/fume/gas/mist/vapors/spray

    P280 - Wear protective gloves/protective clothing/eye protection/face protection

    P302 + P352 - IF ON SKIN: Wash with plenty of soap and water

    P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing