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(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamin, 97 %, Thermo Scientific Chemicals
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamin, 97 %, Thermo Scientific Chemicals
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamin, 97 %, Thermo Scientific Chemicals
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamin, 97 %, Thermo Scientific Chemicals
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamin, 97 %, Thermo Scientific Chemicals
Thermo Scientific Chemicals

(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamin, 97 %, Thermo Scientific Chemicals

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2 g
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Katalognummer L19685.04
auch als L19685-04 bezeichnet
Preis (EUR)
-
Menge:
2 g
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Chemikalien-Kennzeichnungen
CAS55700-44-2
IUPAC Name(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine
Molecular FormulaC26H28FeNP
InChI KeyRCAFPSZHKFOLEE-KVEBOLLKNA-N
SMILES[Fe].c1cccc1.C[C@@H](N(C)C)c1cccc1P(C1=CC=CC=C1)C1=CC=CC=C1
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SpecificationsSpecification SheetDatenblatt
Assay (Non-aqueous acid-base Titration)≥96.0 to ≤104.0%
Melting Point (clear melt)137.0-147.0?C
Optical Rotation-359.5 ± 0.1? (C=0.6 in ethanol)
FormCrystals or powder or crystalline powder
Appearance (Color)White to orange to red to brown
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylamine acts as a ligand used in the enantioselective vinylation of aldehydes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Anwendungen
(R)-(-)-N,N-Dimethyl-1-[(S)-2-(diphenylphosphino)-ferrocenyl]-ethylamin dient als Ligand bei der enantioselektiven Vinylierung von Aldehyden.

Löslichkeit
Nicht in Wasser löslich

Hinweise
Nicht kompatibel mit starken Oxidationsmitteln.
RUO – Research Use Only

Allgemeine Referenzen:

  1. Moschetta, E. G.; Gans, K. M.; Rioux, R. M. Elucidating the roles of enthalpy, entropy, and donor atom in the chelate effect for binding different bidentate ligands on the same metal center. J. Catal. 2014, 309, 11-20.
  2. Li, W. N.; Wang, Z. L. Kumada-Tamao-Corriu cross-coupling reaction of O-based electrophiles with Grignard reagents via C-O bond activation. RSC Adv. 2013, 3 (48), 25565-25575.