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Thermo Scientific Chemicals
4-Chloroanisole, 99%
CAS: 623-12-1 | C7H7ClO | 142.582 g/mol
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Catalog number A11377.30
also known as A11377-30
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Quantity:
250 g
Chemical Identifiers
CAS623-12-1
IUPAC Name1-chloro-4-methoxybenzene
Molecular FormulaC7H7ClO
InChI KeyYRGAYAGBVIXNAQ-UHFFFAOYSA-N
SMILESCOC1=CC=C(Cl)C=C1
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Specifications
Specification Sheet
Specification SheetAppearance (Color)Clear colorless
Refractive Index1.5335-1.5365 @ 20?C
Assay (GC)≥98.5%
FormLiquid
4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
4-Chloroanisole was found to react with Cu (II)-smectite forming a blue clay-organic complex. 4-Chloroanisole was chosen as the main test substrate for the optimisation studies as it is electronically deactivated and thus resistant to oxidative addition and consequently very reluctant to enter a catalytic manifold.
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
RUO – Research Use Only
General References:
- Antonio Monopoli et. al. Glucose as a clean and renewable reductant in the Pd-nanoparticle-catalyzed reductive homocoupling of bromo- and chloroarenes in water. Journal of Organic Chemistry. 2010, 75 (11), 3908-3911 .
- Helge Lemmetyinen,; Jan Konijnenberg,,; Jan Cornelisse,; Cyril A.G.O. Varma. Laser spectroscopic study of the nucleophilic photosubstitution of 4-chloroanisole and 4-fluoroanisole in aqueous solutions . Journal of Photochemistry. 1985, 30(3) , 315-338.