1-Bromo-3-iodobenzene, 98%
1-Bromo-3-iodobenzene, 98%
1-Bromo-3-iodobenzene, 98%
Thermo Scientific Chemicals

1-Bromo-3-iodobenzene, 98%

CAS: 591-18-4 | C6H4BrI | 282.91 g/mol
Quantity:
25 g
100 g
Catalog number A19596.22
also known as A19596-22
Price (JPY)
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Quantity:
100 g
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Chemical Identifiers
CAS591-18-4
IUPAC Name1-bromo-3-iodobenzene
Molecular FormulaC6H4BrI
InChI KeyCTPUUDQIXKUAMO-UHFFFAOYSA-N
SMILESBrC1=CC=CC(I)=C1
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SpecificationsSpecification SheetSpecification Sheet
Appearance (Color)Clear colorless to yellow to brown
FormLiquid
Assay (GC)≥97.5%
Identification (FTIR)Conforms
Refractive Index1.6595-1.6635 @ 20?C
1-Bromo-3-iodobenzene is used in the preparation of 3'-bromo-2,3,4,5,6-pentaethyl-biphenyl by reacting with hex-3-yne. It is also used to prepare 1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3'-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene. Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Bromo-3-iodobenzene is used in the preparation of 3′-bromo-2,3,4,5,6-pentaethyl-biphenyl by reacting with hex-3-yne. It is also used to prepare 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodec-1-ene and 1-(3′-bromophenyl)-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooct-1-ene. Further, it is involved in the preparation of oxygen-tethered 1,6-enynes.

Solubility
Immiscible with water.

Notes
Light sensitive. Incompatible with strong oxidizing agents, strong bases and strong acids. Store in a cool place.
RUO – Research Use Only

General References:

  1. Kanazawa, Y.; Yokota, T.; Ogasa, H.; Watanabe, H.; Hanakawa, T.; Soga, S.; Kawatsura, M. Chemoselective amination of bromoiodobenzenes with diarylamines by palladium/Xantphos or ligand-free copper catalysts. Tetrahedron 2015, 71 (9), 1395-1402.
  2. Sharma, R.; Thakur, K.; Kumar, R.; Kumar, I.; Sharma, U. Distant C-H Activation/Functionalization: A New Horizon of Selectivity Beyond Proximity. Catal. Rev. Sci. Eng. 2015, 57 (3), 345-405.