Chlorobis(2-methoxyphenyl)phosphine, 98+%

Name: Chlorobis(2-methoxyphenyl)phosphine, 98+%
SKU: H25894.03

CAS: 263369-88-6 | C18H17ClO2P- | 331.756 g/mol

Technical SupportCustomer Service

Change view

Quantity:

1 g

5 g

Try the chem dex^TM web app

Catalog number H25894.03

also known as H25894-03

Price (JPY)

Quantity:

1 g

Request bulk or custom format

Chemical Identifiers

CAS263369-88-6

IUPAC Name3,4-bis(2-methoxyphenyl)-1,2-dihydro-1,2-chloraphosphinin-1-uide

Molecular FormulaC18H17ClO2P

InChI KeyWVGQIZOJKMMSSK-UHFFFAOYSA-N

SMILESCOC1=CC=CC=C1C1=C(C=C[Cl-]P1)C1=CC=CC=C1OC

Specifications

Specification Sheet

Appearance (Color)White

FormCrystalline powder

Proton NMRConforms to structure

Phosphorus-31 NMRConforms to structure

Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.

RUO – Research Use Only

General References:

Anna Trifonova; Jarle S. Diesen; Pher G. Andersson Prof. Dr. Asymmetric Hydrogenation of Imines and Olefins Using Phosphine-Oxazoline Iridium Complexes as Catalysts. Chemistry - A European Journal. 2006, 12 (8), 2318-2328.
Sandra Brun; Magda Parera; Anna Pla-Quintana; Anna Roglans; Thierry León; Thierry Achard; Jordi Solà; Xavier Verdaguer; Antoni Riera. Chiral N-phosphino sulfinamide ligands in rhodium(I)-catalyzed [2+2+2] cycloaddition reactions. Tetrahedron. 2010, 66 (46), 9032-9040.