4-Fluoro-1,3-dioxolan-2-one, 98%
4-Fluoro-1,3-dioxolan-2-one, 98%
4-Fluoro-1,3-dioxolan-2-one, 98%
4-Fluoro-1,3-dioxolan-2-one, 98%
Thermo Scientific Chemicals

4-Fluoro-1,3-dioxolan-2-one, 98%

CAS: 114435-02-8 | C3H3FO3 | 106.052 g/mol
Quantity:
25 g
100 g
Catalog number H61502.22
also known as H61502-22
Price (JPY)
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Quantity:
100 g
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Chemical Identifiers
CAS114435-02-8
IUPAC Name4-fluoro-1,3-dioxolan-2-one
Molecular FormulaC3H3FO3
InChI KeySBLRHMKNNHXPHG-UHFFFAOYNA-N
SMILESFC1COC(=O)O1
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SpecificationsSpecification SheetSpecification Sheet
Assay (GC)98%
4-Fluoro-1,3-dioxolan-2-one is used as an electrolyte additive in lithium ion batteries. It also enables the formation of thin, smooth and stable passive solid electrolyte interphase (SEI) layer, which increases the cycling efficiency and discharge capacity retention of the secondary battery. Further, it is used as an intermediate in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-Fluoro-1,3-dioxolan-2-one is used as an electrolyte additive in lithium ion batteries. It also enables the formation of thin, smooth and stable passive solid electrolyte interphase (SEI) layer, which increases the cycling efficiency and discharge capacity retention of the secondary battery. Further, it is used as an intermediate in organic synthesis.

Solubility
Slightly miscible with water.

Notes
Incompatible with strong oxidizing agents and strong bases.
RUO – Research Use Only

General References:

  1. Leung, K.; Rempe, S. B.; Foster, M. E.; Ma, Y.; del la Hoz, J. M. M.; Sai, N.; Balbuena, P. B. Modeling Electrochemical Decomposition of Fluoroethylene Carbonate on Silicon Anode Surfaces in Lithium Ion Batteries. J. Electrochem. Soc. 2014, 161 (3), A213-A221.
  2. Markevich, E.; Salitra, G.; Rosenman, A.; Talyosef, Y.; Chesneau, F.; Aurbach. D. Fluoroethylene carbonate as an important component in organic carbonate electrolyte solutions for lithium sulfur batteries. Electrochem. Commun. 2015, 60, 42-46.
  3. Profatilova, I. A.; Stock, C.; Schmitz, A.; Passerini, S.; Winter, M. Enhanced thermal stability of a lithiated nano-silicon electrode by fluoroethylene carbonate and vinylene carbonate. J. Power Sources 2013, 222, 140-149.