O-Benzylhydroxylamine, 96%, Thermo Scientific Chemicals
O-Benzylhydroxylamine, 96%, Thermo Scientific Chemicals
Thermo Scientific Chemicals

O-Benzylhydroxylamine, 96%, Thermo Scientific Chemicals

Quantity:
5 g
25 g
Catalog number L13601.06
also known as L13601-06
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5 g
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Chemical Identifiers
CAS622-33-3
IUPAC Namehydrogen O-benzylhydroxylamine chloride
Molecular FormulaC7H10ClNO
InChI KeyHYDZPXNVHXJHBG-UHFFFAOYSA-N
SMILES[H+].[Cl-].NOCC1=CC=CC=C1
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SpecificationsSpecification SheetSpecification Sheet
Assay (GC)≥95.0%
Appearance (Color)Clear colorless to white to yellow
FormLiquid
Identification (FTIR)Conforms
Refractive Index1.5375-1.5435 @ 20?C
O-benzylhydroxylamine used in the synthesis of alfa- hydroxybenzylamines from alfa-hydroxyketones. It is also involved in the preparation of hydroxylamines and hydroxyamates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
O-benzylhydroxylamine used in the synthesis of alfa- hydroxybenzylamines from alfa-hydroxyketones. It is also involved in the preparation of hydroxylamines and hydroxyamates.

Solubility
Soluble in dimethylsulfoxide and methanol.

Notes
Store in a cool place. Incompatible with strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Jobbins, M. O.; Majewski, M. W.; Oliver, A. G.; Miller, M. J. Diastereoselective synthesis of a hydroxamate containing bicyclo-[3.2. 0] beta-lactam aminal via ruthenium alkene isomerization and Pd(II)-catalyzed oxidative amidation. Tetrahedron Lett. 2015, 56 (23), 3141-3143.
  2. Jeon, M.; Gupta, S.; Im, Y. W.; Rhee, Y. H.;Park, J. Fast and Complete Transimination of N-H Imines into O-Alkyl Oximes. Asian J. Org. Chem. 2015, 4 (4), 316-319.