Trimethylacetonitrile, 98+%
Trimethylacetonitrile, 98+%
Trimethylacetonitrile, 98+%
Thermo Scientific Chemicals

Trimethylacetonitrile, 98+%

CAS: 630-18-2 | C5H9N | 83.134 g/mol
製品番号(カタログ番号) A12011.14
または、製品番号A12011-14
価格(JPY)
-
数量:
25 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS630-18-2
IUPAC Name2,2-dimethylpropanenitrile
Molecular FormulaC5H9N
InChI KeyJAMNHZBIQDNHMM-UHFFFAOYSA-N
SMILESCC(C)(C)C#N
さらに表示
Appearance (Color)Clear colorless to pale yellow
Identification (FTIR)Conforms
Refractive Index1.3755-1.3795 @ 20?C
Assay (GC)≥98.0%
FormLiquid
Trimethylacetonitrile used as a solvent and as a labile ligand in coordination chemistry. It is also used as an intermediate in organic synthesis. It is used in the presence of titanium(II) chloride and zinc to undergoes reductive coupling reaction of aromatic and aliphatic ketones including acyclic aliphatic ketones to give the corresponding pinacols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Trimethylacetonitrile used as a solvent and as a labile ligand in coordination chemistry. It is also used as an intermediate in organic synthesis. It is used in the presence of titanium(II) chloride and zinc to undergoes reductive coupling reaction of aromatic and aliphatic ketones including acyclic aliphatic ketones to give the corresponding pinacols.

Solubility
Miscible with ethanol, acetone and toluene. Slightly miscible with water.

Notes
Store in a cool place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.
RUO – Research Use Only

General References:

  1. For in situ reaction with vinyl triflates in the synthesis of sterically hindered 2,4,6-trisubstituted pyrimidines, see: Synthesis, 881 (1990); for reaction scheme, see Trifluoromethanesulfonic acid, A1173 .
  2. Bagal, D. B.; Bhanage, B. M. Recent Advances in Transition Metal-Catalyzed Hydrogenation of Nitriles. Adv. Synth. Catal. 2015, 357 (5), 883-900.
  3. Akhtar, N.; Akhtar, W. Prospects, challenges, and latest developments in lithium-air batteries. Int. J. Energy Res. 2015, 39 (3), 303-316.