Search Thermo Fisher Scientific
Element Search
Structure SearchThermo Scientific Chemicals
Benzyl 2,2,2-trichloroacetimidate, 98%, Thermo Scientific Chemicals
Catalog number: A12387.14
25 g, Each
Thermo Scientific Chemicals
Benzyl 2,2,2-trichloroacetimidate, 98%, Thermo Scientific Chemicals
Catalog number: A12387.14
25 g, Each
Quantity
Catalog number: A12387.14
also known as A12387-14
Price (USD)
Price: 102.00
Online price: 90.65
Your price:
Quantity
-
Chemical Identifiers
CAS
81927-55-1
IUPAC Name
benzyl 2,2,2-trichloroethanimidate
Molecular Formula
C9H8Cl3NO
InChI Key
HUZCTWYDQIQZPM-UHFFFAOYSA-N
SMILES
ClC(Cl)(Cl)C(=N)OCC1=CC=CC=C1
Specifications
Specification SheetAppearance (Color)
Clear colorless to pale yellow
Refractive Index
1.5425-1.5465 @ 20?C
Assay (GC)
≥97.5%
Form
Liquid
Description
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Solubility
Miscible with cyclohexane/dichloromethane.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents and strong acids.
Benzyl 2,2,2-trichloroacetimidate is used for the acid-catalyzed benzylation of hydroxy groups. It acts as reagent during the synthesis of funiculosin dimethyl ether and (S)-3-(benzyloxy)-2-methylpropanal. It can also be used for mild esterification of carboxylic acids in the presence of a catalytic amount of BF3 etherate.
Solubility
Miscible with cyclohexane/dichloromethane.
Notes
Moisture and light sensitive. Incompatible with strong oxidizing agents and strong acids.
RUO – Research Use Only
Figures
Documents & Downloads
Certificates
Search by lot number or partial lot number
Frequently asked questions (FAQs)
Citations & References
Search citations by name, author, journal title or abstract text