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化学物質識別子
CAS645-96-5
IUPAC Namephenylsulfanyl
Molecular FormulaC6H5Se
InChI KeyYWBHROUQJYHSOR-UHFFFAOYSA-N
SMILES[Se]C1=CC=CC=C1
さらに表示
仕様
スペックシート
スペックシートFormLiquid
Assay (GC)≥90.0%
Appearance (Color)Clear colorless to yellow
Refractive Index1.6110-1.6190 @ 20?C
It is applied for reactions of phenylselenol and its anion. Benzeneselenol can used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is applied for reactions of phenylselenol and its anion. Benzeneselenol can used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.
Solubility
Not miscible or difficult to mix in water.
Notes
Air sensitive. Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
It is applied for reactions of phenylselenol and its anion. Benzeneselenol can used as starting reagent in the synthesis of monoseleno-substituted 1,3-dienes. It may be used in the synthesis of cationic chalcogenolato-bridged diruthenium complexes.
Solubility
Not miscible or difficult to mix in water.
Notes
Air sensitive. Store away from oxidizing agents and air. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
RUO – Research Use Only
General References:
- Nikolay V Orlov et. al. Exclusive selectivity in the one-pot formation of C-C and C-Se bonds involving Ni-catalyzed alkyne hydroselenation: optimization of the synthetic procedure and a mechanistic study.J Org Chem.,2014,79(24), 12111-12121.
- R.J. Puddephatt and P.J. Thompson. Some reactions of methylplatinum and methylgold compounds with phenylselenol, diphenylphosphine, diphenylarsine, N-bromosuccinimide and 2-nitrophenylsulphenyl chloride.J. Organomet. Chem.,1976,117(4), 395-403.
- For reactions of phenylselenol and its anion, see Diphenyl diselenide, A13919.