Thermo Scientific Chemicals

(1-Propyl)triphenylphosphonium bromide, 99%, Thermo Scientific Chemicals

Catalog number: A12968.18
50 g, Each
Thermo Scientific Chemicals

(1-Propyl)triphenylphosphonium bromide, 99%, Thermo Scientific Chemicals

Catalog number: A12968.18
50 g, Each
Quantity
Catalog number: A12968.18
also known as A12968-18
Price (USD)
Quantity
-

Chemical Identifiers

CAS
6228-47-3
IUPAC Name
triphenyl(propyl)phosphanium bromide
Molecular Formula
C21H22BrP
InChI Key
XMQSELBBYSAURN-UHFFFAOYSA-M
SMILES
[Br-].CCC[P+](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1
Appearance (Color)
White
Form
Crystals or powder or crystalline powder
Assay (Titration ex Bromide)
≥98.5 to ≤101.5%
Identification (FTIR)
Conforms
Melting Point (clear melt)
232-238?C

Description

It is employed as a catalyst for the carboxylation of styrene oxide and as a reactant involved in epoxidation of arylalkenes, boration of allylic epoxides, Wittig reactions, selective dimerization of α-olefins, and synthesis of indoles. It has also been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is employed as a catalyst for the carboxylation of styrene oxide and as a reactant involved in epoxidation of arylalkenes, boration of allylic epoxides, Wittig reactions, selective dimerization of α-olefins, and synthesis of indoles. It has also been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A.

Solubility
Soluble in water.

Notes
Hygroscopic. Store away from oxidizing agents, humidity and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
RUO – Research Use Only

Figures

Documents & Downloads

Certificates

    Frequently asked questions (FAQs)

    Citations & References

    Search citations by name, author, journal title or abstract text