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Thermo Scientific Chemicals
Hexamethylditin, 97%
CAS: 661-69-8 | C6H18Sn2 | 327.63 g/mol
化学物質識別子
CAS661-69-8
IUPAC Namehexamethyldistannane
Molecular FormulaC6H18Sn2
InChI KeyCCRMAATUKBYMPA-UHFFFAOYSA-N
SMILESC[Sn](C)(C)[Sn](C)(C)C
さらに表示
仕様
スペックシート
スペックシートAssay (GC)≥96.0%
Refractive Index1.5385-1.5435 @ 20°C
Identification (FTIR)Conforms
Appearance (Color)Colorless to pale yellow
FormClear to hazy or turbid liquid
It is used to prepare aryl tin compounds for microwave-assisted Stille cross-coupling with halo pyridines or copper-mediated O-arylation of phenols.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
It is used to prepare aryl tin compounds for microwave-assisted Stille cross-coupling with halo pyridines or copper-mediated O-arylation of phenols.
Solubility
Not miscible or difficult to mix in water.
Notes
Air Sensitive. Keep away from oxidizing agents, heat and air. Store under inert gas.
It is used to prepare aryl tin compounds for microwave-assisted Stille cross-coupling with halo pyridines or copper-mediated O-arylation of phenols.
Solubility
Not miscible or difficult to mix in water.
Notes
Air Sensitive. Keep away from oxidizing agents, heat and air. Store under inert gas.
RUO – Research Use Only
General References:
- Olov A. Wallner and Kálmán J. Szabó. Regioselective Palladium-Catalyzed Electrophilic Allylic Substitution in the Presence of Hexamethylditin.Org. Lett.,2004,4(9), 1563-1566.
- E.W. Abel.; S. Moorhouse. Utilization of hexamethylditin in the synthesis of organotin-transitional metal complexes.J. Organomet. Chem.1970,24(3), 687-690.