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Thermo Scientific Chemicals
Methyl 1-cyclohexene-1-carboxylate, 97%
CAS: 18448-47-0 | C8H12O2 | 140.182 g/mol
化学物質識別子
CAS18448-47-0
IUPAC Namemethyl cyclohex-1-ene-1-carboxylate
Molecular FormulaC8H12O2
InChI KeyKXPWRCPEMHIZGU-UHFFFAOYSA-N
SMILESCOC(=O)C1=CCCCC1
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Clear colorless to pale yellow
Refractive Index1.4745-1.4795 @20?C
FormLiquid
Assay (GC)≥96.0%
Identification (FTIR)Conforms
Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
Solubility
Immiscible with water.
Notes
Incompatible with strong oxidizing agents and bases.
Methyl 1-cyclohexene-1-carboxylate is used in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols and methyl -7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
Solubility
Immiscible with water.
Notes
Incompatible with strong oxidizing agents and bases.
RUO – Research Use Only
General References:
- Johnson, M. R.; Gauuan, J. F.; Guo, C.; Guzzo, P. R.; Le, V. D.; Shenoy, R. A.; Hamby, J.; Roark, H.; Stier, M.; Mangette, J. E. Synthesis and Characterization of Novel Bi-and Tricyclic α-Amino Acids. Synth. Commun. 2011, 41 (18), 2769-2793.
- Tian, G. Q.; Yang, J.; Rosa-Perez, K. γ-Oxygenation of α, β-Unsaturated Esters by Vinylogous O-Nitroso Mukaiyama Aldol Reaction. Org. Lett. 2010, 12 (21), 5072-5074.