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Thermo Scientific Chemicals
Chlorobis(2-methoxyphenyl)phosphine, 98+%
CAS: 263369-88-6 | C18H17ClO2P- | 331.756 g/mol
化学物質識別子
CAS263369-88-6
IUPAC Name3,4-bis(2-methoxyphenyl)-1,2-dihydro-1,2-chloraphosphinin-1-uide
Molecular FormulaC18H17ClO2P
InChI KeyWVGQIZOJKMMSSK-UHFFFAOYSA-N
SMILESCOC1=CC=CC=C1C1=C(C=C[Cl-]P1)C1=CC=CC=C1OC
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)White
FormCrystalline powder
Proton NMRConforms to structure
Phosphorus-31 NMRConforms to structure
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
Solubility
Reacts with water.
Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.
Chlorobis(2-methoxyphenyl)phosphine is used as a reactant for cycloadditions reactions, asymmetric hydrogenation and allylic substitution, asymmetric hydrogenation of imines and olefins. It is also used as a reactant for synthesis of ferrocene-based chiral diphosphine, catalysts for C-C cross coupling reactions, palladium complexes.
Solubility
Reacts with water.
Notes
Air and moisture sensitive. Incompatible with oxidizing agents, bases, water/ moisture.
RUO – Research Use Only
General References:
- Anna Trifonova; Jarle S. Diesen; Pher G. Andersson Prof. Dr. Asymmetric Hydrogenation of Imines and Olefins Using Phosphine-Oxazoline Iridium Complexes as Catalysts. Chemistry - A European Journal. 2006, 12 (8), 2318-2328.
- Sandra Brun; Magda Parera; Anna Pla-Quintana; Anna Roglans; Thierry León; Thierry Achard; Jordi Solà; Xavier Verdaguer; Antoni Riera. Chiral N-phosphino sulfinamide ligands in rhodium(I)-catalyzed [2+2+2] cycloaddition reactions. Tetrahedron. 2010, 66 (46), 9032-9040.