2-(Tri-n-butylstannyl)thiazole, 96%
2-(Tri-n-butylstannyl)thiazole, 96%
2-(Tri-n-butylstannyl)thiazole, 96%
Thermo Scientific Chemicals

2-(Tri-n-butylstannyl)thiazole, 96%

CAS: 121359-48-6 | C15H29NSSn | 374.174 g/mol
製品番号(カタログ番号) H51090.03
または、製品番号H51090-03
価格(JPY)
-
数量:
1 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS121359-48-6
IUPAC Name2-(tributylstannyl)-1,3-thiazole
Molecular FormulaC15H29NSSn
InChI KeyWUOFQGMXQCSPPV-UHFFFAOYSA-N
SMILESCCCC[Sn](CCCC)(CCCC)C1=NC=CS1
さらに表示
Assay from Suppliers CofA≥95.0%
FormLiquid
Used as reagent for arylation of thiazole by Stille cross-coupling.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used as reagent for arylation of thiazole by Stille cross-coupling.

Solubility
Not miscible or difficult to mix.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
RUO – Research Use Only

General References:

  1. Rüdiger Wittenberg; Jiri Srogl; Masahiro Egi; and Lanny S. Liebeskind. Ketone Synthesis under Neutral Conditions. Cu(I) Diphenylphosphinate-Mediated, Palladium-Catalyzed Coupling of Thiol Esters and Organostannanes. Org. Lett,. 2003, 5(17), 3033-3035.
  2. Hao Li; Hao Yang; and Lanny S. Liebeskind. Synthesis of High Enantiopurity N-Protected α-Amino Ketones by Thiol Ester-Organostannane Cross-Coupling Using pH-Neutral Conditions. Org. Lett., 2008, 10(19), 4375-4378.