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Thermo Scientific Chemicals
Allylmagnesium chloride, 1M in MeTHF
CAS: 2622-05-1 | C3H5ClMg | 100.83 g/mol
化学物質識別子
CAS2622-05-1
IUPAC Namechloro(prop-2-en-1-yl)magnesium
Molecular FormulaC3H5ClMg
InChI KeyPLYLAFITHJUEGX-UHFFFAOYSA-M
SMILESCl[Mg]CC=C
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仕様
スペックシート
スペックシートConcentration0.7-1.2M
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Solubility
It reacts violently with water.
Notes
Air & moisture sensitive. Stable under recommended storage conditions.
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Solubility
It reacts violently with water.
Notes
Air & moisture sensitive. Stable under recommended storage conditions.
RUO – Research Use Only
General References:
- Minglong Yuan; Dan Liu; Chengdong Xiong; Xianmo Deng. Polymerization of lactides and lactones 6. Synthesis of polydl-lactide and polyethylene glycol-co-polydl-lactide copolymer with allylmagnesium chloride. European Polymer Journal. 1999, 35, (12),21390-2145
- Toshihiro Nishikawa; Hiroshi Shinokubo; Koichiro Oshima. Regioselective allylmetalation of allenes with tetraallylmanganate or allylmagnesium chloride under MnCl2 catalysis. Org. Lett. 2003, 5, (24),4623-4626