D-Epoxone, 98%
D-Epoxone, 98%
D-Epoxone, 98%
Thermo Scientific Chemicals

D-Epoxone, 98%

CAS: 18422-53-2 | C12H18O6 | 258.27 g/mol
製品番号(カタログ番号) L18989.03
または、製品番号L18989-03
価格(JPY)
-
数量:
1 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS18422-53-2
IUPAC Name2,2,5',5'-tetramethyl-tetrahydro-2H-spiro[[1,3]dioxolo[4,5-c]pyran-6,2'-[1,4]dioxolan]-7-one
Molecular FormulaC12H18O6
InChI KeyIVWWFWFVSWOTLP-UHFFFAOYNA-N
SMILESCC1(C)OC2COC3(COC(C)(C)O3)C(=O)C2O1
さらに表示
Appearance (Color)White
Assay (GC)≥97.5%
Identification (FTIR)Conforms
Melting Point (clear melt)97-106°C
Optical Rotation-122.0 ± 1.5° (c=1 in chloroform)
さらに表示
D-Epoxone is a chemical reagent used for enantioselective epoxidation of alkenes. It is involved in the synthesis of Irciniastatin (A and B), which are used as antitumor compounds. It is used as cytotoxic secondary metabolite.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
D-Epoxone is a chemical reagent used for enantioselective epoxidation of alkenes. It is involved in the synthesis of Irciniastatin (A and B), which are used as antitumor compounds. It is used as cytotoxic secondary metabolite.

Solubility
Soluble in chloroform and methanol.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
RUO – Research Use Only

General References:

  1. Tran, A. T.; Luo, B.; Jagadeesh, Y.; Auberger, N.; Désiré, J.; Nakagawa, S.; Kato, A.; Zhang, Y.; Blériot, Y.; Sollogoub, M. Synthesis of pyrrolidine-based analogues of 2-acetamidosugars as N-acetyl-d-glucosaminidase inhibitors. Carbohydr. Res. 2015, 409, 56-62.
  2. Ren, X-D.; Zhao, N.; Xu, S.; Lü, H-N.; Ma, S-G.; Liu, Y-B.; Li, Y.; Qu, J.; Yu, S-S. Total synthesis of illicidione A and illihendione A. Tetrahedron 2015, 71 (29), 4821-4829.