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Thermo Scientific Chemicals
Methylgermanium trichloride, 97%
CAS: 993-10-2 | CH9Cl3Ge | 200.06 g/mol
化学物質識別子
CAS993-10-2
スペックシートThis Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Methylgermanium trichloride is used as a precursor for the synthesis of five-coordinated spirocyclic anionic methylgermanates by reacting with catechol. It is also involved in the photo-chemical adsorption of organo-germanium on a hydrogen terminated atomically flat silicon surface using xenon excimer light.
Solubility
Miscible with ether.
Notes
Sensitive to moisture and reacts violently with water. Also hydrolysis takes place when contact with water. Incompatible with oxidizing agents and bases.
Methylgermanium trichloride is used as a precursor for the synthesis of five-coordinated spirocyclic anionic methylgermanates by reacting with catechol. It is also involved in the photo-chemical adsorption of organo-germanium on a hydrogen terminated atomically flat silicon surface using xenon excimer light.
Solubility
Miscible with ether.
Notes
Sensitive to moisture and reacts violently with water. Also hydrolysis takes place when contact with water. Incompatible with oxidizing agents and bases.
RUO – Research Use Only
General References:
- Yakubovich, S.; Kalikhman, I.; Kost, D. Facile central-element exchange in neutral hexacoordinate germanium and silicon complexes; synthesis and characterization of germanium complexes. Dalton Trans. 2010, 39 (39), 9241-9244.
- Takaya, J.; Nakamura, S.; Iwasawa, N. Synthesis, Structure, and Catalytic Activity of Palladium Complexes Bearing a Tridentate PXP-Pincer Ligand of Heavier Group 14 Element (X= Ge, Sn). Chem. Lett. 2012, 41 (9), 967-969.