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Thermo Scientific Chemicals
Trimethyl orthobenzoate, 98%
CAS: 707-07-3 | C10H14O3 | 182.219 g/mol
化学物質識別子
CAS707-07-3
IUPAC Name(trimethoxymethyl)benzene
Molecular FormulaC10H14O3
InChI KeyIECKAVQTURBPON-UHFFFAOYSA-N
SMILESCOC(OC)(OC)C1=CC=CC=C1
さらに表示
仕様
スペックシート
スペックシートFormLiquid
Identification (FTIR)Conforms
Appearance (Color)Clear colorless
Assay (GC)≥97.5%
Refractive Index1.4875-1.4915 @ 20?C
Trimethyl orthobenzoate was used in the preparation of 5-phenyl-4,6-dipyrrin and 2,3-orthoester derivatives of ethyl-1-thio-α-L-rhamnopyranoside. It reacts with indole to prepare indol-3-yl-phenyl-methanone.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Trimethyl orthobenzoate was used in the preparation of 5-phenyl-4,6-dipyrrin and 2,3-orthoester derivatives of ethyl-1-thio-α-L-rhamnopyranoside. It reacts with indole to prepare indol-3-yl-phenyl-methanone.
Solubility
Soluble in organic solvents.
Notes
Moisture Sensitive. Protect from humidity and water. Store under dry inert gas. Incompatible with oxidizing agents and moisture.
Trimethyl orthobenzoate was used in the preparation of 5-phenyl-4,6-dipyrrin and 2,3-orthoester derivatives of ethyl-1-thio-α-L-rhamnopyranoside. It reacts with indole to prepare indol-3-yl-phenyl-methanone.
Solubility
Soluble in organic solvents.
Notes
Moisture Sensitive. Protect from humidity and water. Store under dry inert gas. Incompatible with oxidizing agents and moisture.
RUO – Research Use Only
General References:
- R G Hicks; L Ohrström; G W Patenaude. Spin distributions, ring conformations, and spiroconjugation in phosphaverdazyl radicals. Inorganic Chemistry. 2001, 40 (8), 1865-1870.
- Reaction with BF3 etherate gives the selective alkylating agent, phenyldimethoxycarbenium tetrafluoroborate, stable for a few weeks at 0°: Synth. Commun., 19, 2307 (1989).