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Thermo Scientific Chemicals
2-Bromobenzyl bromide, 98%
CAS: 3433-80-5 | C7H6Br2 | 249.933 g/mol
化学物質識別子
CAS3433-80-5
IUPAC Name1-bromo-2-(bromomethyl)benzene
Molecular FormulaC7H6Br2
InChI KeyLZSYGJNFCREHMD-UHFFFAOYSA-N
SMILESBrCC1=CC=CC=C1Br
さらに表示
仕様
スペックシート
スペックシートAppearance (Color)Colorless to white to cream to yellow to orange
Melting Point (clear melt)29.0-35.0?C
Assay (GC)≥97.5%
FormLumps or fused solid or clear liquid as melt
Identification (FTIR)Conforms
さらに表示
2-Bromobenzyl bromide was used in the synthesis of substituted quinazolines and 1,2,3,4-tetrahydroquinazolines, 2- and 3-substituted indenes, tris-2-bromotribenzylamine3.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
2-Bromobenzyl bromide was used in the synthesis of substituted quinazolines and 1,2,3,4-tetrahydroquinazolines, 2- and 3-substituted indenes, tris-2-bromotribenzylamine3.
Solubility
Insoluble in water.
Notes
Store away from strong bases and oxidizing agents. Incompatible with amines, alcohols, steel.
2-Bromobenzyl bromide was used in the synthesis of substituted quinazolines and 1,2,3,4-tetrahydroquinazolines, 2- and 3-substituted indenes, tris-2-bromotribenzylamine3.
Solubility
Insoluble in water.
Notes
Store away from strong bases and oxidizing agents. Incompatible with amines, alcohols, steel.
RUO – Research Use Only
General References:
- Ronald L. Halterman; Chengian Zhu. Efficient synthesis of 2- and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr(II)i(II)-mediated carbonyl addition sequence. Tetrahedron letters 1999, 40, 7445-7448.
- Yao Dai; Xiujuan Feng; Hesong Liu; Hua Jiang and Ming Bao. Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. J. Org. Chem.2011, 76, (24)10068-10077.