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Thermo Scientific Chemicals
Diisopropyl methylphosphonate, 95%, Thermo Scientific Chemicals
化学物質識別子
CAS1445-75-6
仕様
スペックシート
スペックシートRefractive Index1.4070-1.4130 @ 20?C
Appearance (Color)Clear colorless to yellow
Assay (GC)≥94.0%
Identification (FTIR)Conforms
FormLiquid
Diisopropyl methylphosphonate is used as a precursor to prepare beta-keto phosphonates. It acts as an intermediate for Horner-Wadsworth-Emmons olefination of carbonyl compounds.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Diisopropyl methylphosphonate is used as a precursor to prepare beta-keto phosphonates. It acts as an intermediate for Horner-Wadsworth-Emmons olefination of carbonyl compounds.
Solubility
Miscible with water.
Notes
Store in cool place. Incompatible with acids, oxidizing agents, alkali metals, strong oxidizing agents, strong acids, acid chlorides, acid anhydrides, reducing agents, strong reducing agents and phosphorus halides.
Diisopropyl methylphosphonate is used as a precursor to prepare beta-keto phosphonates. It acts as an intermediate for Horner-Wadsworth-Emmons olefination of carbonyl compounds.
Solubility
Miscible with water.
Notes
Store in cool place. Incompatible with acids, oxidizing agents, alkali metals, strong oxidizing agents, strong acids, acid chlorides, acid anhydrides, reducing agents, strong reducing agents and phosphorus halides.
RUO – Research Use Only
General References:
- Reacts with esters giving ß-keto phosphonates, useful intermediates for Horner-Wadsworth-Emmons olefination of carbonyl compounds, cf Dimethyl methyl phosphonate, A14268.
- Terzic, O.; Gregg, H.; Voogt, P. Identification of chemicals relevant to the Chemical Weapons Convention using the novel sample-preparation methods and strategies of the Mobile Laboratory of the Organization for the Prohibition of Chemical Weapons. TrAC, Trends Anal. Chem. 2015, 65, 151-166.
- Maza, W. A.; Vetromile, C. M.; Kim, C.; Xu, X.; Zhang, X. P.; Larsen, R. W. Spectroscopic Investigation of the Noncovalent Association of the Nerve Agent Simulant Diisopropyl Methylphosphonate (DIMP) with Zinc(II) Porphyrins. J. Phys. Chem. A 2013, 117 (44), 11308-11315.