Potassium thiocyanate, 98%
Potassium thiocyanate, 98%
Potassium thiocyanate, 98%
Thermo Scientific Chemicals

Potassium thiocyanate, 98%

CAS: 333-20-0 | CKNS | 97.176 g/mol
製品番号(カタログ番号) A13731.36
または、製品番号A13731-36
価格(JPY)
-
数量:
500 g
一括またはカスタム形式をリクエストする
化学物質識別子
CAS333-20-0
IUPAC Namepotassium cyanosulfanide
Molecular FormulaCKNS
InChI KeyZNNZYHKDIALBAK-UHFFFAOYSA-M
SMILES[K+].[S-]C#N
さらに表示
FormCrystals or powder or crystalline powder
Water Content (Karl Fischer Titration)≤2.5%
Appearance (Color)White
Assay (Argentometric Titration)≥97.5 to ≤102.5%
Potassium thiocyanate is used in the preparation of ethylenesulfide, lead thiocyante, which is used in the conversion of acyl chloride to thiocyanates. It is also used in solid state NMR of heavy-metal nuclei which results in the preparation of several mercury-thiocyanate and selenocyanate compounds as potential models. It finds application in cosmetic and personal care product formulations as a skin conditioning agent. It is also used in moisturizers and oral care products.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Potassium thiocyanate is used in the preparation of ethylenesulfide, lead thiocyante, which is used in the conversion of acyl chloride to thiocyanates. It is also used in solid state NMR of heavy-metal nuclei which results in the preparation of several mercury-thiocyanate and selenocyanate compounds as potential models. It finds application in cosmetic and personal care product formulations as a skin conditioning agent. It is also used in moisturizers and oral care products.

Solubility
Soluble in water, acetone and alcohol.

Notes
Hygroscopic. Air, light and moisture sensitive. Incompatible with nitric acids, active halogen compounds and strong bases.
RUO – Research Use Only

General References:

  1. Reaction with primary amine hydrohalide salts provides a useful synthesis of N-substituted and N,N'-disubstituted thioureas: Synthesis, 1569 (2000).
  2. Zhang, G.; Chen, B.; Guo, X.; Guo, S.; Yu, Y. Iron(II)-Promoted Synthesis of 2-Aminothiazoles via CN Bond Formation from Vinyl Azides and Potassium Thiocyanate. Adv. Synth. Catal. 2015, 357 (5), 1065-1069.
  3. Wang, S.; Wu, X.; Wang, Y.; Li, Y.; Wang, L.; Chen, Y.; Li, B. Dissolution behavior of deacetylated konjac glucomannan in aqueous potassium thiocyanate solution at low temperature. RSC Adv. 2014, 4 (42), 21918-21923.