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Triethyl phosphonoacetate, 98+%, Thermo Scientific Chemicals
製品番号（カタログ番号）： A14120.0E
2500 g, Each
化学物質識別子
CAS
867-13-0
IUPAC Name
ethyl 2-(diethoxyphosphoryl)acetate
Molecular Formula
C8H17O5P
InChI Key
GGUBFICZYGKNTD-UHFFFAOYSA-N
SMILES
CCOC(=O)CP(=O)(OCC)OCC
仕様
スペックシートAssay (GC)
≥98.0%
Refractive Index
1.4300-1.4340 @ 20?C
Appearance (Color)
Clear colorless
Identification (FTIR)
Conforms
Form
Liquid
概要
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
Triethyl phosphonoacetate serves as a reactant used in Horner-Wadsworth-Emmons reactions, Tsuji-Trost type reactions, Intramolecular Heck-type cyclization and isomerizations and Intramolecular aryne-ene reactions. In Horner-Wadsworth-Emmons reaction, it is utilized as a reagent to prepare chiral 2-methylcyclopropanecarboxylic acid from (S)-propylene oxide.
Solubility
Slightly miscible with water.
Notes
Incompatible with strong oxidizing agents.
RUO – Research Use Only
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